TECHNICAL FIELD
The invention relates to an optical disk having a label
surface (a surface opposite to an information recording surface) at which a visible
image can be recorded.
BACKGROUND ART
Networks such as the Internet and high vision TV have rapidly
become popular, and broadcasting of high definition television (HDTV) is being started.
Under the circumstances, optical disks of large capacity in which image information
can be conveniently recorded at a low cost are demanded. While DVD-R (Digital Versatile
Disk) sufficiently plays a role as an optical disk of large capacity at present,
demands for larger capacity and higher density have increased more and more, and
development of optical recording media capable of coping with such demands is also
necessary. Accordingly, optical disks of larger capacity capable of recording at
high density by light having a shorter wavelength compared with DVD-R have been
under development.
In conventional optical disks, laser beams are usually
irradiated from the substrate side. However, for achieving higher density, pickups
using short wavelength lasers and objective lenses having high numerical apertures
(NA) have increasingly been used. For example, a Blu-ray disk uses a blue-violet
laser in the vicinity of 405 nm and an objective lens having an NA of 0.85. In such
optical recording media using a short-wavelength and high-NA optical system, the
influence of coma aberration caused by the warpage of the disk can be considerable.
Accordingly, for the sake of eliminating the influence
of coma aberration, irradiation of a laser beam for recording and reproducing has
been performed through a cover layer having a thickness of about 0.1 mm which is
far thinner than conventional substrates (for example, that of a CD is 1.2 mm in
thickness, and that of a DVD is 0.6 mm in thickness) to attempt to achieve improvement
with regard to errors in recording and reproducing caused by coma aberration.
The above-described optical disks, for example rewritable
phase change optical recording media, have a medium structure composed of a cover
layer, a transparent adhesive layer, a dielectric layer, a recording layer, a dielectric
layer, a reflecting layer and a substrate in this order from the laser beam entrance
surface side. In a blue-ray disk, the total thickness of the cover layer and the
transparent adhesive layer is about 0.1 mm, and the thickness of the substrate is
about 1.1 mm. As the cover layer, a plastic film is used.
In such a configuration, the thickness of the substrate
is significantly different from that of the cover layer, and thus the disk tends
to be warped when used under conditions where environmental temperature significantly
changes. It is difficult to reduce the deformability even by variously changing
the material of the cover layer.
On the other hand, Blu-ray disks as mentioned above have
a large recording capacity and are therefore capable of recording various types
of information. Accordingly, it will be convenient if the content of the recorded
information can be displayed on the disks. An optical recording medium has been
proposed which is capable of displaying by altering the contrast between the surface
and background by the use of a laser marker at the label surface (for example, see
Patent Document 1). However, this technology is concerned with optical disks such
as DVD.
Furthermore, in Patent Documents 2, 3, and 4, optical information recording media
capable of forming an image by a laser beam are disclosed.
- Patent Document 1: Japanese Patent Application Laid-Open (
JP-A) No. 11-66617
- Patent Document 2:
JP-ANo. 2000-113516
- Patent Document 3:
JP-ANo. 2001-283464
- Patent Document 4:
JP-A No. 2000-173096
DISCLOSURE OF THE INVENTION
PROBLEMS TO BE SOLVED BY THE INVENTION
The invention has been accomplished in consideration of
the above conventional problems, and is intended to achieve the following object.
That is, an object of the invention is to provide an optical disk comprising an
image recording layer (visible information recording layer) disposed at a label
surface, wherein the occurrence of warpage is inhibited.
MEANS FOR SOLVING THE PROBLEMS
As a result of intensive study for solving the above problems,
the inventor has achieved the invention. That is, the invention is an optical disk
in which an image recording layer and a first cover layer are formed in this order
on one surface side of a substrate, and an information recording layer and a second
cover layer are formed in this order on the other surface side of the substrate.
The thicknesses of the first cover layer and the second
cover layer are preferably substantially the same as each other. Furthermore, the
materials of the first cover layer and the second cover layer are preferably the
same material. Furthermore, the materials of the first cover layer and the second
cover layer are preferably cellulose triacetate.
EFFECT OF THE INVENTION
According to the invention, an optical disk comprising
an image recording layer (visible information recording layer) disposed at a label
surface, wherein the occurrence of warpage is inhibited, can be provided.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a schematic view of main parts representing an
example of a configuration of the optical disk of the invention.
BEST MODE FOR CARRYING OUT THE INVENTION
The optical disk of the invention is further described
below. In the optical disk of the invention, an image recording layer and a first
cover layer are formed in this order on one surface side of a substrate, and an
information recording layer and a second cover layer are formed in this order on
the other surface side of the substrate. Since the first cover layer and the second
cover layer are provided on both surfaces of the substrate, the warpage which can
be a practical problem is not occurred, even when environmental temperature significantly
changes. Furthermore, the image recording layer formed on the substrate allows an
index display of the information recorded in the optical disk and free formation
of intended designs. The optical disk of the invention preferably further has a
reflecting layer, a barrier layer, and a protective layer as appropriate.
The optical disk of the invention may be either of a recordable
type or of a rewritable type having an information recording layer capable of recording
and reproducing information by a laser beam, and is preferably of a recordable type.
The information recording system may be of a phase change type or of a dye type,
and is not particularly limited, but preferably of a dye type.
In order to effectively inhibit the occurrence of warpage
due to the difference of the thickness between the substrate and the cover layer,
the thicknesses of the first cover layer and the second cover layer are preferably
substantially the same as each other. The term "substantially the same" means that
the ratio between the thickness of the first cover layer t1 and that
of the second cover layer t2 (t1/t2) is 0.8 to
1.2, and preferably 0.9 to 1.1.
For the sake of substantially equalizing the thicknesses
of the first cover layer and the second cover layer, and more effectively inhibiting
the occurrence of warpage, the materials of the layers are preferably the same.
The material of the cover layers, which will be further described in detail later,
is preferably a transparent sheet comprising polycarbonate or cellulose triacetate,
and more preferably a transparent sheet comprising cellulose triacetate in consideration
of scratch resistance, birefringence, and cost.
An example of a configuration of the optical disk of the
invention a illustrated below by reference to Fig. 1. Fig. 1 is a schematic view
representing an example of a configuration of the optical disk of the invention.
As shown in Fig. 1, in the optical disk of the invention
100, a reflecting layer 20A, an information recording layer 30, a barrier layer
50A, an adhesive layer 60A, and a sheet 70A as a first cover layer are formed on
one surface side of a substrate 10. Furthermore, a reflecting layer 20B, an image
recording layer 40, a barrier layer 50B, an adhesive layer 60B, and a transparent
sheet 70B as a second cover layer are formed on the other surface side of the substrate
10. When the first cover layer and the second cover layer are not a sheet or a transparent
sheet, the adhesive layer comprising an adhesive or tackiness agent is not indispensable.
Furthermore, the sheet 70A may be colored as long as it has a high transmittance
with respect to a laser beam.
Each of the layers of the optical disk of the invention
may be formed by a known method. Furthermore, the order of formation is not particularly
limited. The elements composing the optical disk of the invention (e.g., a substrate
and layers) are described below. Each of the layers included in the optical disk
of the invention may be composed of a single layer or a plurality of layers.
[Substrate]
The substrate may be arbitrarily selected from various
materials which have been used as substrates for conventional optical disks. Examples
of substrate materials include glass, polycarbonate, acrylic resins such as polymethyl
methacrylate, vinyl chloride resins such as polyvinyl chloride or vinyl chloride
copolymers, epoxy resins, amorphous polyolefin, and polyester. These materials may
be used in combination. Among the above-described materials, polycarbonate is preferable
from the viewpoint of moisture resistance, dimensional stability, cost, and the
like.
In general, the thickness of the substrate is preferably
1.2±0.2 mm, more preferably 1.2±0.1 mm, and in particular, may be appropriately
determined in the range of 0.5 to 1.4 mm in consideration of the thickness of the
image recording layer, barrier layer, and transparent protective layer, which work
for forming a visible image.
Furthermore, a guide groove for tracking or an asperity
(groove) representing information such as address signals is formed on at least
one surface side of the substrate (a surface side on which an information recording
layer is formed). In order to achieve higher storage density, it is preferable to
use a substrate having a groove with a track pitch that is narrower than the track
pitch in a CD-R or DVD-R. The track pitch of the groove is preferably in the range
of 200 to 400 nm, and more preferably in the range of 250 to 350 nm. The depth of
the groove (groove depth) is preferably in the range of 20 to 150 nm, and more preferably
in the range of 25 to 80 nm. The width of the groove is preferably in the range
of 50 to 250 nm, and more preferably in the range of 100 to 200 nm.
A guide groove for tracking may also be formed on the other
surface side (a surface side on which an image recording layer is formed) of the
substrate. In this case, the guide groove is preferably formed in compliance with
the shape of the groove formed on the substrate. When a guide groove is formed on
the image recording layer as above, image recording can be performed with a laser
pickup being tracked, and the position of the pickup can be precisely controlled,
whereby a detailed image can be recorded. Furthermore, the groove provided on the
image recording layer iridizes the surface by the effect of interference of light.
Furthermore, an undercoat layer may be provided on one
surface side of the substrate for the purposes of improvement of planarity, enhancement
of adhesive force, and prevention of degradation of the information recording layer.
Examples of the material of the undercoat layer include polymer substances such
as polymethyl methacrylate, acrylic acid-methacrylic acid copolymer, styrene-maleic
anhydride copolymer, polyvinyl alcohol, N-methylol acrylamide, styrene-vinyl toluene
copolymer, chlorosulfonated polyethylene, nitro cellulose, polyvinyl chloride, chlorinated
polyolefin, polyester, polyimide, vinyl acetate-vinyl chloride copolymer, ethylene-vinyl
acetate copolymer, polyethylene, polypropylene, or polycarbonate; and surface modifiers
such as silane coupling agents. The undercoat layer can be formed by dissolving
or dispersing the above-described substances in a suitable solvent to prepare a
coating liquid, followed by applying the coating liquid onto the surface of a substrate
by spin coating, dip coating, extrusion coating, or other coating methods. The thickness
of the undercoat layer is generally in the range of 0.005 to 20 µm, and preferably
in the range of 0.01 to 10 µm.
[Reflecting layer]
The reflecting layer is, when it is formed on one surface
side, intended for improving the reflectivity in reproduction of information. When
the layer is formed on the other surface side, it is intended for improving the
visibility of a visible image.
A light reflective substance which is a material of the
reflecting layer is preferably a substance having a high reflectivity with respect
to a laser beam. Examples thereof include metals and semimetals such as Mg, Se,
Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Co, Ni, Ru, Rh, Pd, Ir, Pt, Cu,
Ag, Au, Zn, Cd, Al, Ga, In, Si, Ge, Te, Pb, Po, Sn, or Bi, stainless steel, and
semiconductor materials. These substance may be used alone, in combination of two
or more of them, or as alloy. Among them, Cr, Ni, Pt, Cu, Ag, Au, Al, and stainless
steel are preferable. Au, Ag, Al, or alloys thereof are more preferable, and Ag,
Al, or alloys thereof are further preferable, and Ag alloys (Ag-Nd-Cu, Ag-Pd-Cu,
Ag-In-Cu, or Ag-Bi-Nd) are most preferable.
The reflecting layer can be formed by, for example, vapor
deposition, sputtering, or ion plating of the above-described light reflective substances
on the information recording layer or the image recording layer. The thickness of
the reflecting layer is generally in the range of 10 to 300 nm, and preferably in
the range of 50 to 200 nm.
[Information recording layer]
The information recording layer is a layer on which code
information (encoded information) such as digital information is recorded. Examples
thereof include dye type (recordable type) and phase change type ones. The layer
is not particularly limited, but preferably of a dye type.
Specific examples of the dye contained in the dye type
information recording layer include a cyanine dye, oxonol dye, metal complex dye,
azo dye, and phthalocyanine dye. Among them, an oxonol dye is particularly preferable.
Furthermore, dyes described in
JP-A Nos. 4-74690
,
8-127174
,
11-53758
,
11-334204
,
11-334205
,
11-334206
,
11-334207
,
2000-43423
,
2000-108513
,
2000-158818
and others are preferably used.
Furthermore, in the dye type information recording layer,
organic compounds such as a triazole compound, triazine compound, cyanine compound,
melocyanine compound, amino butadiene compound, phthalocyanine compound, cinnamic
acid compound, viologen compound, azo compound, oxonol benzoxazole compound, and
benzotriazole compound are preferably used. Among these compounds, a cyanine compound,
amino butadiene compound, benzotriazole compound, phthalocyanine compound, and oxonol
compound are particularly preferable.
The dye type information recording layer can be formed
by vapor deposition, sputtering, CVD, solvent coating, or other methods, and is
preferably formed by solvent coating.
When a solvent coating method is employed, the dye type
information recording layer is formed by dissolving a recording substance such as
a dye in a solvent together with a quencher, binder, or the like to prepare a coating
liquid, subsequently applying the coating liquid onto a substrate to form a coated
film, followed by drying. The concentration of the recording substance (dye) in
the coating liquid is generally in the range of 0.01 to 15% by mass, preferably
in the range of 0.1 to 10% by mass, more preferably in the range of 0.5 to 5% by
mass, and most preferably in the range of 0.5 to 3% by mass.
Examples of the solvent for the coating liquid include
esters such as butyl acetate, ethyl lactate, or cellosolve acetate; ketones such
as methyl ethyl ketone, cyclohexanone, or methyl isobutyl ketone; chlorinated hydrocarbons
such as dichloro methane, 1,2-dichloro ethane, or chloroform; amides such as dimethylformamide;
hydrocarbons such as methyl cyclohexane; ethers such as dibutyl ether, diethyl ether,
tetrahydrofuran, or dioxane; alcohols such as ethanol, N-propanol, isopropanol,
n-butanol, or diacetone alcohol; fluorine solvents such as 2,2,3,3-tetrafluoropropanol;
and glycol ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl
ether, or propylene glycol monomethyl ether.
The above-described solvents may be used alone or in combination
of two or more in consideration of the solubility of the dye to be used. To the
coating liquid, various additives such as an antioxidant, UV absorbing agent, plasticizing
agent, or lubricant may be further added according to the intended use.
When a binder is used, examples thereof include natural
organic polymer substances such as gelatin, cellulose derivatives, dextran, rosin,
and rubber; and synthesis organic polymers such as: hydrocarbon resins such as polyethylene,
polypropylene, polystyrene, or polyisobutylene; vinyl resins such as polyvinyl chloride,
polyvinylidene chloride, or polyvinyl chloride-polyvinyl acetate copolymer; acrylic
resins such as polymethyl acrylate or polymethyl methacrylate; and initial condensates
of thermosetting resins such as polyvinyl alcohol, chlorinated polyethylene, epoxy
resin, butyral resin, rubber derivatives, or phenol-formaldehyde resin.
When a binder is included in the materials of the dye type
information recording layer, the usage amount of the binder is generally in the
range of 0.01 to 50 times the mass of the dye, and preferably in the range of 0.
1 to 5 times the mass of the dye.
Examples of the coating method for the above-described
solvent coating include a spray method, spin coat method, dip method, roll coat
method, blade coat method, doctor roll method, and screen printing method.
The thickness of the dye type information recording layer
is generally in the range of 10 to 500 nm, preferably in the range of 15 to 300
nm, and more preferably in the range of 20 to 150 nm. The dye type information recording
layer may be composed of a single layer or a plurality of layers.
The dye type information recording layer may contain various
antifading agents in order to improve the light resistance thereof As the antifading
agent, a singlet oxygen quencher is generally used. As the singlet oxygen quencher,
known ones described in publications such as patent descriptions may be used. Specific
examples thereof include those described in
JP-ANos. 58-175693
,
59-31194
,
60-18387
,
60-19586
,
60-19587
,
60-35054
,
60-36190
,
60-36191
,
60-44554
,
60-44555
,
60-44389
,
60-44390
,
60-54892
,
60-47069
,
68-209995
, and
4-25492
, Japanese Patent Application Publication (
JP-B) Nos. 1-38680
, and
6-26028
,
German Patent No. 350399
, and
Nihon Kagaku Kaishi (Journal of the Chemical Society of Japan), October 1992,
p. 1141
.
The usage amount of the above-described antifading agent
such as a singlet oxygen quencher is usually in the range of 0.1 to 50% by mass
relative to the mass of the dye, preferably in the range of 0.5 to 45% by mass,
further preferably in the range of 3 to 40% by mass, and particularly preferably
in the range of 5 to 25% by mass.
Furthermore, specific examples of the materials composing
the phase change type information recording layer include a Sb-Te alloy, Ge-Sb-Te
alloy, Pd-Ge-Sb-Te alloy, Nb-Ge-Sb-Te alloy, Pd-Nb-Ge-Sb-Te alloy, Pt-Ge-Sb-Te alloy,
Co-Ge-Sb-Te alloy, In-Sb-Te. alloy, Ag-In-Sb-Te alloy, Ag-V-In-Sb-Te alloy, and
Ag-Ge-ln-Sb-Te alloy. Among them, a Ge-Sb-Te alloy and Ag-ln-Sb-Te alloy are preferable
because they allow multiple times of rewriting.
The thickness of the phase change type information recording
layer is preferably 10 to 50 nm, and more preferably 15 to 30 nm. The phase change
type information recording layer can be formed by a vapor phase thin film deposition
method such as a sputtering method or vacuum deposition method.
[Barrier layer]
The barrier layer is preferably provided primarily for
the purpose of preventing the deterioration of dyes in the information recording
layer, and further for enhancing the storage stability of the image recording layer.
The material used for the barrier layer is not particularly
limited as long as it is a material which transmits a laser beam for image recording-to
the image recording layer, and is capable of carrying out the above-described functions.
For example, it is a material having a low gas or moisture permeability, and preferably
a dielectric, material. The barrier layer preferably has a transmittance of 80%
or more, more preferably 90% or more, and further preferably 95% or more with respect
to a laser beam for recording an image on the image recording layer.
Specifically, as the material used for the barrier layer,
materials composed of nitrides, oxides, carbides, or sulfides of Zn, Si, Ti, Te,
Sn, Mn, Ge, or the like are preferable, ZnS, MoO2, GeO2 TeO,
SiO2, TiO2, ZuO, ZnS-SiO2, SnO2, and
ZnO-Ga2O3 are preferable, and ZnS-SiO2, SnO2,
and ZnO-Ga2O3 are more preferable.
The barrier layer can be formed on the recording layer
by a vacuum film forming method such as vacuum deposition, DC sputtering, RF sputtering,
or ion plating. The film forming conditions in these vacuum film forming methods
may be appropriately adjusted according to the material and the intended thickness
and density of the film to be formed. The thickness of the barrier layer is preferably
in the range of 1 to 200 nm, more preferably in the range of 2 to 100 nm, and further
preferably in the range of 3 to 70nm.
[Protective layer]
The protective layer is an optional layer which is provided
for the purpose of physically and chemically protecting the information recording
layer and/or the image recording layer.
Examples of the material used for the protective layer
include inorganic substances such as ZnS, ZnS-SiO2, SiO, SiO2,
MgF2, SnO2, or Si3N4, and organic substances
such as thermoplastic resins, thermosetting resins, or UV curable resins.
When the protective layer is formed using a thermoplastic
resin or thermosetting resin, the layer may also be formed by dissolving the resin
in an appropriate solvent to prepare a coating liquid, followed by applying and
drying the coating liquid. In cases where a UV curable resin is used, the protective
layer may be formed by applying the coating liquid, followed by irradiating UV light
for curing. To the coating liquid, various additives such as an anti-static agent,
antioxidant, or UV absorbing agent may be further added according to the purpose.
The thickness of the protective layer is generally in the range of 0.1 µm to
1 mm.
[Image recording layer]
On the image recording layer, visible images (visible information)
such as characters, graphics, pictures or the like intended by the user are recorded
by a laser beam. Examples of the visible image include the title and content information
of the disk, thumbnail of the content, related pictures, designed pictures, copyright
information, date and time of recording, recording method, recording format, and
bar code.
The visible image recorded on the image recording layer
means a visually recognizable image, and includes all types of visually recognizable
information such as a character (string), picture, or graphics. Furthermore, examples
of character information include authorized user designation information, period
of use designation information, times of use designation information, rental information,
resolution designation information, layer designation information, user designation
information, copyright owner information, copyright number information, manufacturer
information, information on date of manufacture, information on date of sale, information
on sale shops or sellers, information on used set numbers, region designation information,
language designation information, application designation information, product user
information, and information on numbers in use.
The image recording layer suffices if it is capable of
recording image information such as a character, image, or picture by irradiation
of a laser beam in a visually recognizable manner. As the constituent material thereof,
the recording substance (e.g., dye or phase change recording material) described
with regard to the previously-mentioned information recording layer can be preferably
used, and the layer preferably contains a dye from the viewpoint of visibility.
Furthermore, in the optical disk of the invention, the
constituent of the previously-described information recording layer (recording substance:
dye or phase change recording material) and the constituent of the image recording
layer may be the same as or different from each other, but preferably different
from each other because the required properties differ between the information recording
layer and the image recording layer. Specifically, the constituent of the information
recording layer is preferably superior in recording and reproducing properties,
and the constituent of the image recording layer preferably increases the contrast
of the recorded visible image.
In particular, when a dye is used as the constituent of
the image recording layer, among the previously-described dyes, a cyanine dye, phthalocyanine
dye, azo dye, azo metal complex, oxonol dye, and leuco dye are preferable from the
viewpoint of improving the contrast of the recording image. Furthermore, one of
the information recording layer or the image recording layer may be of a phase change
type, and the other may be of a dye type. In this case, it is preferable that the
information recording layer is of a phase change type, and the image recording layer
is of a dye type.
The image recording layer can be formed by dissolving a
previously-described dye in a solvent to prepare a coating liquid, followed by applying
the coating liquid. As the solvent, the same solvent as that used for the preparation
of the previously-described coating liquid for the information recording layer may
be used. Other additives, coating method, and the like may follow those for the
previously-described information recording layer.
The thickness of the image recording layer is preferably
in the range of 0.01 to 200 µm, more preferably in the range of 0.05 to 20
µm, and further preferably in the range of 0.1 to 5 µm.
[Adhesive layer]
The adhesive layer in the optical disk of the invention
is formed when a transparent sheet is used as a first cover layer and/or a second
cover layer.
When an adhesive is used as the adhesive layer, for example,
a UV curable resin, EB curable resin, thermosetting resin, or the like is preferably
used, and in particular a UV curable resin is preferably used. Furthermore, in order
to prevent the warpage of the optical disk, the UV curable resin constituting the
adhesive layer preferably has a low cure shrinkage. Examples of such UV curable
resins include SD-640 manufactured by Dainippon Ink And Chemicals, Incorporated.
These adhesives are applied at least one surface to be
bonded by roll coating, spin coating, screen printing, or other methods. Then the
adhesive is cured to form an adhesive layer. The thickness of the formed adhesive
layer is preferably in the range of 10 to 100 µm, and more preferably in the
range of 20 to 60 µm from the viewpoints of development of adhesive strength
and leveling effect.
Furthermore, a transparent sheet coated with a tackiness
agent may be used, that is, a tackiness agent may be used as the adhesive layer
in place of the above-described adhesive. As the tackiness agent, acryl, rubber,
and silicon tackiness agents may be used, and acryl tackiness agents are preferable
from the viewpoint of transparency and durability. The acryl tackiness agent is
preferably a copolymer in which 2-ethylhexyl acrylate, n-butyl acrylate, or the
like as a main ingredient is polymerized with a short-chain alkyl acrylate or methacrylate
for enhancing cohesive force, such as methyl acrylate, ethyl acrylate, or methyl
methacrylate, and acrylic acid, methacrylic acid, an acrylamide derivative, maleic
acid, hydroxyl ethyl acrylate, glycidyl acrylate, or the like which can serve as
crosslinking point with a crosslinking agent. The glass transition temperature (Tg)
and crosslinking density can be varied by appropriately adjusting the type and mixing
ratio between the main ingredient, the short chain component, and the component
for imparting a crosslinking point.
Examples of the crosslinking agent used in combination
with the above-described tackiness agent include isocyanate crosslinking agents.
Examples of the isocyanate crosslinking agents include isocyanates such as tolylene
diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, xylylene
diisocyanate, naphthylene-1,5-diisocyanate, o-toluidine isocyanate, isophorone diisocyanate,
or triphenyl methane triisocyanate, reaction products of these isocyanates and polyalcohols,
and polyisocyanates produced by the condensation of isocyanates. Examples of commercial
products of the above isocyanates include COLONATE L, COLONATE HL, COLONATE 2030,
COLONATE 2031, MILLIONATE MR, and MILLIONATE HTL manufactured by Nippon Polyurethane
Industry Co., Ltd.; TAKENATE D-102, TAKENATE D-110N, TAKENATE D-200, and TAKENATE
D-202 manufactured by Takeda Pharmaceutical Company Limited; and DESMODUR L, DESMODUR
IL, DESMODUR N, and DESMODUR HL manufactured by Sumitomo Bayer Co., Ltd.
[Cover layer]
The first cover layer and the second cover layer are formed,
as previously mentioned, for preventing the warpage of the optical disk. Furthermore,
they also physically and chemically protect the inside of the optical disk. The
cover layers are transparent for irradiating a laser beam to the information recording
layer and the image recording layer. More specifically, the layers preferably have
a transmittance of 80% or more, more preferably 90% or more, and further preferably
95% or more with respect to both of a laser beam and reflected light.
As the transparent sheet (sheet) as a cover layer, as previously
described, specifically, polycarbonate, acrylic resins such as polymethyl methacrylate;
vinyl chloride resins such as polyvinyl chloride, or vinyl chloride copolymers;
epoxy resin; amorphous polyolefin; polyester; cellulose triacetate, and the like
are preferable, and among them, polycarbonate or cellulose triacetate is more preferable,
and cellulose triacetate is further preferable.
The thickness of the transparent sheet, which is appropriately
selected according to the laser beam for image recording and NA, in the invention,
is preferably in the range of 10 to 600 µm, more preferably in the range of
30 to 200 µm, and further preferably in the range of 50 to 110 µm.
When an adhesive is used as the adhesive layer, for example,
"a specified amount of adhesive is applied onto a barrier layer at the surface to
be bonded, and thereon a transparent sheet is placed", or "a specified amount of
adhesive is applied onto a transparent sheet, and the coated surface is fitted to
a barrier layer at the surface to be bonded", and subsequently the adhesive is uniformly
spread between the surface to be bonded and the transparent sheet by spin coating,
and cured using a curing means suitable to the adhesive (for example, UV irradiation)
to form a cover layer comprising a transparent sheet. When the adhesive is a UV
curable resin, it may be cured by UV irradiation for bonding.
As the adhesive to be applied, the above-described curable
resins may be used as they are, or a coating liquid prepared by dissolving the above-described
curable resin in an appropriate solvent such as methyl ethyl ketone or ethyl acetate
may be used.
Furthermore, when a tackiness agent is used as the adhesive
layer, a cover layer is formed by, for example, uniformly applying a specified amount
of tackiness agent onto the barrier layer at the surface to be bonded, and thereon
placing a transparent sheet, followed by curing, or by uniformly applying a specified
amount of tackiness agent onto one surface of a transparent sheet to form a coating
film of the tackiness agent, and pressing the coating film against the surface to
be bonded by a vacuum adhesion system or rubber roller for bonding, followed by
curing. As a transparent sheet, a tacky film on which a tacky layer has been previously
provided may be used.
Other embodiments of the cover layers include a transparent
curable resin layer. As the material for the transparent curable resin layer, UV
curable resins, EB curable resins, and thermosetting resins, which are suitable
as the adhesive used for the above-described adhesive layer, may be used, and among
them, UV curable resins are preferably used. Furthermore, for the sake of effectively
preventing the warpage of the optical disk, the UV curable resin for constituting
the adhesive layer preferably has a low cure shrinkage. Examples of such UV curable
resins include SD-640, a UV curable resin manufactured by Dainippon Ink And Chemicals,
Incorporated.
In such cases, the thickness of the cover layers may be
specified according to the layer configuration of the optical disk, and preferably
in the range of 10 to 600 µm, more preferably in the range of 30 to 200 µm,
and further preferably in the range of 50 to 110 µm from the viewpoints of
the ability of protecting the inside of the optical disk and transparency.
A hard coat layer may be provided on at least either one
of the laser beam incident surfaces of the cover layers in the invention for preventing
scratches on the laser beam incident surfaces during manufacturing or using the
optical disk.
(Image recording method)
Image recording on the image recording layer of the optical
disk of the invention is performed using the optical disk of the invention and a
recording apparatus at least capable of recording image information on the image
recording layer of the optical disk.
In the first place, the recording apparatus used for recording in the optical disk
of the invention is further described below.
In the optical disk of the invention, recording of an image
on the image recording layer, and recording of optical information on the information
recording layer can be performed by one optical disk drive (recording apparatus)
having recording functions for both the layers. When such an optical disk drive
is used, recording is performed on either one of the image recording layer or the
information recording layer, then the disk is turned upside down, followed by recording
on the other layer. Alternatively, by changing the focus position between the information
recording layer and the image recording layer from the surface at the information
recording layer side, recording can be carried out on either one of the image recording
layer or the information recording layer, and immediately after that, recording
can be carried out on the other layer. In this case, there is no need to turn the
disk upside down.
The optical disk drive having a function of recording of
a visible image on the image recording layer is, for example, described in
JP-A Nos. 2003-203348
and
2003-242750
.
The recording apparatus for recording optical information
on the information recording layer and recording a visible image on the image recording
layer comprises at least a laser pickup for irradiating a laser beam, a rotating
device for rotating the optical disk, and a transfer device for changing the relative
position of the pickup to the disk in the radial direction. The objective lens and
laser used for the pickup may be known ones according to the optical disk in which
an image is recorded.
The method of recording a visible image on the image recording
layer using the recording apparatus is further described below. In the first place,
the laser pickup is focused to the image recording layer of the optical disk being
rotated by the rotating device, and subsequently the pickup is allowed to track
the formed groove for tracking and to relatively move along the surface of the optical
disk, and a laser beam (for example 780 nm) modulated according to the image data
such as a character or picture to be formed is irradiated from the second cover
layer side toward the image recording layer while synchronized with the relative
movement, whereby a visible image is recorded. Such a configuration is described
in, for example,
JP-A Nb. 2002-203321
.
Recording of a visible image on the image recording layer
does not necessarily require tracking. In such cases, for example, a method of recording
a visible image by laser irradiation controlled by a stepping motor or the like
according to intended image data is used.
(Information recording method)
In the next place, recording of information (digital information)
on the information recording layer using the recording apparatus is further described.
When the information recording layer is of a dye type, a laser beam (350 to 500
nm, preferably 400 to 440 nm) is irradiated by the laser pickup from the first cover
layer side while the above-described unrecorded optical disk is rotated by the rotating
device at a predetermined recording linear velocity. The irradiated beam is absorbed
by the dye in the information recording layer to locally increase the temperature,
and intended pits are generated to change the optical properties in the region,
whereby information is recorded. The information recorded on the information recording
layer is reproduced by laser irradiation from the laser pickup toward the information
recording layer of the optical disk in a rotated state.
Examples of the laser beam source irradiating an oscillation
wavelength of 350 to 500 nm include a blue-violet semiconductor laser having an
oscillation wavelength in the range of 390 to 415 nm, and a blue-violet SHG laser
having a center oscillation wavelength of about 430 nm. Furthermore, the numerical
aperture (NA) of the objective lens used for the pickup is preferably 0.7or more,
and more preferably 0.80 or more for enhancing the recording density.
In the next place, the phase change type information recording
layer is further described. The phase change type information recording layer is
composed of the above-described materials, and is capable of repeating phase change
between a crystal phase and amorphous phase by laser beam irradiation. When information
is recorded, concentrated laser beam pulses are irradiated for a short period of
time to partially melt the phase change type information recording layer. The melted
portion is rapidly cooled by thermal diffusion, solidifies, and forms recording
marks in an amorphous state. When information is erased, a laser beam is irradiated
to the recording marks to heat the portion to a temperature equal to or lower than
the melting point of the information recording layer but equal to or higher than
the crystallization temperature, and then the portion is slowly cooled to crystallize
the amorphous state recording marks to return to the original unrecorded state.
EXAMPLES
The invention is illustrated by following Examples, but
the invention is not limited to them.
(Example 1)
Ag was sputtered on a substrate having a thickness of 1.0
mm and a diameter of 120 mm and composed of an injection molded polycarbonate resin
(trade name: PANLITE AD5503, polycarbonate manufactured by Teijin Chemicals Ltd.)
having a spiral groove (depth:40 nm, width: 120 nm, track pitch: 320 nm) at a side
having a groove to form a reflecting layer having a thickness of 70 nm.
12 g of dye A (ORASOL-BLUE GN: manufactured by Ciba Specialty
Chemicals, maximum absorption: 340 nm, 640 nm), which is a phthalocyanine organic
compound, was mixed with 1 L of 2,2,3,3-tetrafluoropropanol and dissolved therein
by ultrasonic treatment for 2 hours, whereby a coating liquid for forming a recording
layer was prepared. Using the coating liquid, an information recording layer having
a thickness of 70 nm was formed on the reflecting layer by a spin coat method.
Furthermore, Ag was sputtered on the substrate at a side
having no information recording layer to form a reflecting layer having a thickness
of 70 nm.
Onto the reflecting layer formed as described above, a
coating liquid, which had been prepared by mixing 12 g of dye A (ORASOL-BLUE GN:
manufactured by Ciba Specialty Chemicals, maximum absorption: 340 nm, 640 nm) with
1 L of 2,2,3,3-tetrafluoropropanol, and dissolving therein by ultrasonic treatment
for 2 hours, was applied by a spin coat method to form an image recording layer.
Subsequently, the layer was heated and dried in a clean oven at 80°C for 30
minutes. The thickness of the image recording layer was 100 nm. Subsequently, a
barrier layer having a thickness of 7 nm was formed using a target composed of 7
parts by mass of ZnO and 3 parts by mass of Ga2O3 on each
side by a sputtering method.
Polycarbonate films having a thickness of 80 µm coated
with a tackiness agent (first and second cover layers) were respectively bonded
on the barrier layers, whereby an optical disk was prepared. The thickness of the
adhesive layer of the tackiness agent after bonding was 20 µm.
(Example 2)
An optical disk was prepared in the same manner as Example
1, except that as the first cover layer and the second cover layer, cellulose triacetate
films (trade name: FUJITACK, manufactured by Fuji Photo Film Co., Ltd., thickness:
80 µm) were used in place of the polycarbonate films.
(Comparative Example)
An optical disk was prepared in the same manner as Example
1, except that no reflecting layer, no image recording layer, no barrier layer,
and no cover layer was formed on the other surface side of the substrate, and the
thickness of the substrate was 1.1 mm.
The optical disks of Examples 1 and 2, and Comparative
Example were stored at 80°C, 85%RH, for 96 hours and observed for the changes
by the environmental temperature. The optical disks of Examples 1 and 2 scarcely
warped, but the optical disk of Comparative Example warped which gave a practical
problem.
Furthermore, with respect to the optical disks of Examples
1 and 2, the pencil hardness of the cover layers on both the sides were measured.
As a result, the optical disk of Example 2 using a cellulose triacetate film had
a pencil hardness of HB, and that of the optical disk of Example 1 was 4B. That
is, it was confirmed that the optical disk of Example 2 had high hardness and excellent
scratch resistance.
EXPLANATION OF REFERENCE NUMERALS
- 10 : substrate
- 20A, 20B : reflecting layer
- 30 : information recording layer
- 40 : image recording layer
- 50A, 50B: barrier layer
- 60A, 60B : adhesive layer
- 70A, 70B : (transparent) sheet
- 100 : optical disk